石墨负极材料形态对LiFePO4动力电池性能的影响
收稿日期: 2016-02-29
修回日期: 2016-04-05
网络出版日期: 2016-06-27
基金资助
广东省科技计划项目(2014B010128010,2014B010123002,2015B010135010)
Impacts of Graphite Negative Materials Morphology on the Performance of LiFePO4 Power Battery
Received date: 2016-02-29
Revised date: 2016-04-05
Online published: 2016-06-27
本文分别以树脂包覆天然石墨(RCNG)、人造石墨(AG)和中间相碳微球(MCMB)为负极材料,制备了三种不同的圆柱形磷酸铁锂(LiFePO4)动力电池。通过X射线衍射分析仪(XRD)和扫描电子显微镜(SEM)对材料的晶体结构与形貌进行表征,并采用多种手段测试了各动力电池的电化学性能。结果显示,磷酸铁锂/中间相碳微球(LFP/MCMB)电池表现出较为优异的电化学低温、倍率和循环性能,其在 −20℃下的1 C容量保持率为61.04%,6 C高倍率容量保持率和温升分别为87.52%和24.8℃,3 C循环1 000次后容量保持率为93.81%。
陈 鹏 , 钱 龙 , 邓昌源 , 王海涛 , 焦奇方 , 刘家捷 , 饶睦敏 . 石墨负极材料形态对LiFePO4动力电池性能的影响[J]. 新能源进展, 2016 , 4(3) : 195 -200 . DOI: 10.3969/j.issn.2095-560X.2016.03.005
Three different cylindrical lithium iron phosphate (LiFePO4) power batteries were fabricated by using resin-coated natural graphite (RCNG), artificial graphite (AG) and mesophase carbon microbeads (MCMB) as negative material, respectively. Crystalline structure and morphology of the materials were characterized by X-ray diffraction analyzer (XRD) and scanning electron microscopy (SEM). Electrochemical performance of each power battery was tested by various charge/discharge means. The results showed that the lithium iron phosphate/mesophase carbon microbeads (LFP/MCMB) battery exhibited better electrochemical performance in low temperature, rate and cycle performance. It remained 61.04% of 1 C capacity retention at −20°C, capacity retention and temperature elevation at 6 C high-rate were respectively 87.52% and 24.8°C, and capacity retention at 3 C rate was 93.81% after 1 000 cycles.
Key words: LiFePO4; graphite; power battery; electrochemical performance
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