纤维素类碳水化合物转化为糠醛的研究进展

谈  金; 王晨光; 陈伦刚; 徐  莹; 张  琦; 马隆龙

doi:10.3969/j.issn.2095-560X.2018.01.001

新能源进展 >

2018 , Vol. 6 >Issue 1: 1 - 7

DOI: https://doi.org/10.3969/j.issn.2095-560X.2018.01.001

论文

纤维素类碳水化合物转化为糠醛的研究进展

谈金 ,
王晨光 ,
陈伦刚 ,
徐莹 ,
张琦 ,
马隆龙

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1. 中国科学院广州能源研究所，广州 510640；
2. 中国科学院可再生能源重点实验室，广州 510640；
3. 广东省新能源和可再生能源研究开发与应用重点实验室，广州 510640

谈金（1984-），男，博士，助理研究员，主要从事生物质转化与利用的研究。

收稿日期: 2018-01-02

修回日期: 2018-02-13

网络出版日期: 2018-02-28

基金资助

国家自然科学基金项目（51536009）；
广东省特支计划青年拔尖人才项目（2015TQ01N652）；
中国科学院“百人计划”项目

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Progress on Conversion of Cellulosic Carbohydrates into Furfural

TAN Jin ,
WANG Chen-guang ,
CHEN Lun-gang ,
XU Ying ,
ZHANG Qi ,
MA Long-long

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1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. CAS Key Laboratory of Renewable Energy, Guangzhou 510640, China;
3. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China

Received date: 2018-01-02

Revised date: 2018-02-13

Online published: 2018-02-28

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摘要

糠醛是一种用于制备高附加价值液体燃料和其他精细化学品的重要的生物质平台化合物。通常，木质纤维素中的半纤维素在水介质中经酸催化剂作用解聚得到五碳糖后进一步脱水可转化为糠醛，该工艺技术已趋于成熟并用于工业化生产。纤维素在水或一般的双相反应体系中解聚为六碳糖后脱水通常生成5-羟甲基糠醛与乙酰丙酸，而难以甚至不能转化为糠醛。最近的一些文献报道了纤维素类碳水化合物在特定的反应介质中经酸催化剂作用后可转化为糠醛，且提出了不同的反应历程。基于当前研究背景，本文针对纤维素类碳水化合物转化为糠醛的反应特点，综述了已有报道中纤维素类碳水化合物转化为糠醛的反应机理、反应路径和反应体系的特点及反应介质对该反应的影响。最后，对未来纤维素类碳水化合物转化为糠醛的研究方向和发展前景进行了展望。

关键词： 纤维素; 碳水化合物; 反应介质; 糠醛; 协同催化

本文引用格式

谈金 , 王晨光 , 陈伦刚 , 徐莹 , 张琦 , 马隆龙 . 纤维素类碳水化合物转化为糠醛的研究进展[J]. 新能源进展, 2018 , 6(1) : 1 -7 . DOI: 10.3969/j.issn.2095-560X.2018.01.001

Abstract

Furfural is an important platform chemical for synthesizing high value-added liquid fuels and other fine chemicals. Usually, hemicellulose contained in lignocellulose can be hydrolyzed into pentose and further dehydrated into furfural over acid catalyst in pure water medium easily. This is a mature technology which has been applied in the industrialization. Hexose derived from cellulose can be dehydrated over an acid catalyst in water to form 5-hydroxymethylfurfural and levulinic acid, while furfural is barely generated in water or even in the general biphasic reaction system by using solid or liquid acid catalysts. Recently, some literatures showed that furfural can be achieved from cellulosic carbohydrates with high yield only in the combined reaction system of special reaction medium and acid catalyst, and different reaction pathways corresponding to reaction systems were proposed. Based on the present research situation, this review focus on the characteristics of reaction mechanism, reaction pathway, reaction system and summarize the effect of reaction medium on conversion of cellulosic carbohydrates into furfural. Finally, the future research direction and development significance on conversion of cellulosic carbohydrates into furfural were prospected.

Key words： cellulose; carbohydrate; reaction medium; furfural; synergistic catalysis

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