电化学催化还原二氧化碳研究进展

赖洁; 杨楠; 袁健发; 曾嘉瑛; 马丽

doi:10.3969/j.issn.2095-560X.2019.05.007

新能源进展 >

2019 , Vol. 7 >Issue 5: 429 - 435

DOI: https://doi.org/10.3969/j.issn.2095-560X.2019.05.007

电化学催化还原二氧化碳研究进展

赖洁 ,
杨楠 ,
袁健发 ,
曾嘉瑛 ,
马丽

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暨南大学化学与材料学院,广州 510632

赖洁（1994-）,女,硕士研究生,主要从事过渡金属电催化二氧化碳还原体系研究。马丽（1985-）,女,博士,副研究员,硕士生导师,主要从事均相和多相催化体系研究。

收稿日期: 2019-03-05

修回日期: 2019-06-19

网络出版日期: 2019-10-29

基金资助

广东省自然科学基金项目（2017A030310409）; 暨南大学科研培育与创新基金研究项目（21617319）

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Recent Progresses in Electrocatalytic Reduction of Carbon Dioxide: A Review

LAI Jie ,
YANG Nan ,
YUAN Jian-fa ,
ZENG Jia-ying ,
MA Li

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College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, China

Received date: 2019-03-05

Revised date: 2019-06-19

Online published: 2019-10-29

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摘要

目前,能源和环境问题备受关注。一方面,大气层中二氧化碳的平衡受到破坏,其含量不断增加,严重影响了地球生态环境。另一方面,催化剂促进二氧化碳向能源分子的转化,不仅缓解了环境压力,也从一定程度上减轻了能源短缺问题。二氧化碳的资源化再利用在解决能源危机与环境问题方面意义深远,而产物选择性、电流效率以及催化剂的稳定性是目前研究电催化二氧化碳还原反应的主要难点。本文就异相电催化二氧化碳还原的研究现状进行了综述,对二氧化碳还原的电解质体系、主要产物、电极材料的选择和影响以及二氧化碳电化学还原面临的挑战及应对策略等进行了讨论。同时,对开发出成本低、稳定性好、效率高、选择性高的催化剂,尤其是直接电催化二氧化碳还原转化为醇和碳氢化合物的催化策略等进行了展望。

关键词： 电催化; 二氧化碳还原; 催化剂; 选择性

本文引用格式

赖洁 , 杨楠 , 袁健发 , 曾嘉瑛 , 马丽 . 电化学催化还原二氧化碳研究进展[J]. 新能源进展, 2019 , 7(5) : 429 -435 . DOI: 10.3969/j.issn.2095-560X.2019.05.007

Abstract

Nowadays, energy crisis and environmental issues attract a wide attention. On one hand, the concentration of carbon dioxide increases in atmosphere year by year which has already threaten the ecosystem on earth. On the other hand, converting carbon dioxide to fuel molecules with catalysts release not only environmental issues but also the energy crisis. The conversation and utilization of carbon dioxide by electrochemistry is a promising solution for energy crisis and environmental issues. However, the selectivity, current efficiency and stability of electrocatalysts are the key issues faced by the commercialization of carbon dioxide conversation. Based on the review of the research progress on heterogeneous electrochemical reduction of carbon dioxide, the relationships among the reduction products, faraday efficiency of reduction products and electrocatalysts, as well as the possible solutions to the problems faced currently by the electrocatalytic reduction of carbon dioxide were discussed. For the purpose of commercialization of carbon dioxide conversation and utilization, eletctrocatalysts with low-price, good stability, high efficiency and selectivity towards products should be developed. More importantly, researches should find a way to convert carbon dioxide to alcohol or hydrocarbon fuels efficiently.

Key words： electrocatalysis; reduction of carbon dioxide; catalysts; selectivity

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