木质素改性热塑性酚醛树脂的研究进展
收稿日期: 2013-11-06
修回日期: 2013-12-12
网络出版日期: 2013-12-27
基金资助
国家863项目(2013AA050703)
The Progress in Study of Lignin Modified Thermoplastic Phenolic Resin
National Engineering Laboratory for Biomass Chemical Utilization, Key and Open Laboratory on Forest Chemical Engineering, State Forestry Administration, Key Laboratory of Biomass Energy and Material, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry(CAF), Nanjing 210042, China
Received date: 2013-11-06
Revised date: 2013-12-12
Online published: 2013-12-27
周静 , 胡立红 , 周永红 . 木质素改性热塑性酚醛树脂的研究进展[J]. 新能源进展, 2013 , 1(3) : 240 -244 . DOI: 10.3969/j.issn.2095-560X.2013.03.007
Lignin, as a renewable natural organic polymer material, can partially replace phenol to react with formaldehyde; however, the application in industry is limited by its low activity. As fossil resources are depleted, the application of bioresources in phenolic resin attracts more and more attention. This paper summarized main modification ways of thermoplastic phenolic resin with lignin and application of lignin in phenolic resin molding compound. In addition, the development of the lignin in molding material is expected.
Key words: lignin; blending; copolymerization; thermoplastic phenolic resin; molding material
[1] 蒋挺大. 木质素[M]. 北京: 化学工业出版社, 2001.
[2] 黎先发, 罗学刚. 木质素在塑料中的应用研究进展[J]. 塑料, 2004, 33(4): 58-61.
[3] HÜttermann A, Mai C, Kharazipour A. Modification of lignin for the production of new compounded materials[J]. Applied Microbiology and Biotechnology, 2001, 55(4): 387-394.
[4] 曲景奎, 周桂英, 隋智慧, 等. HCR工艺在造纸废水治理中的应用[J]. 环境污染治理技术与设备, 2002, 3(1): 74-77.
[5] 罗继红, 汤志刚. 木质素与塑料共混技术研究进展[J]. 合成树脂及塑料, 2005, 22(4): 81-84.
[6] 黎先发, 罗学刚. 木质素在塑料中的应用进展[J]. 中华纸业, 2004, (6): 54-57.
[7] 方红霞, 吴强林, 张雷. 液化木质素磺酸钙基环保酚醛胶黏剂的合成. 林产化学与工业, 2009, 29(4): 92-95.
[8] 程明娟, 连海兰, 李涛. 超声波法活化麦草碱木素及用于PF胶黏剂的研究. 林产工业, 2012, 39(2): 31-34.
[9] Pucciariello R, Villani V, Bonini C, et a1. Physical properties of straw lignin-based polymer blends[J]. Polymer, 2004, 45(12): 4159-4169.
[10] Cazacu G, Pascu M C, Profire L, et a1. Lignin role in a complex polyolefin blend[J]. Industrial Crops and Products, 2004, 20(2): 261-273.
[11] Femandes D M, Winkler H A A, Job A E, et a1. Thermal and photochemical stability of poly(vinyl alcoho1)/ modified lignin blends[J]. Polym Degradation and Stability, 2006, 91(5): l192-1201.
[12] Velasquez J A, Ferrando F, Salvado J. Effects of kraft lignin addition in the production of binderless fiberboard from steam exploded Misscanthus sinensis[J]. Industrial Crops and Products, 2003, 8(1): 17-23.
[13] Chan W G, Wooten J B, Baliga V L, et a1. Characterization of chars from pyrolysis of lignin[J]. Fuel, 2004, 83(11): 1469-1482.
[14] Thielemans W, Can E, Morye S S, et al. Novel applications of lignin in composite materials[J]. Journal of Applied Polymer Science, 2002, 83(2): 323-331.
[15] Celeghini R M S, Lancas F M. Optimization of the direct liquefaction of lignin obtained from sugarcane bagasse[J]. Energy Sources, 2001, 23(4): 369-375.
[16] Oasmaa A, Alen R, Meier D. Catalytic hydro-treatment of some technical lignins[J]. Bioresour Technol, 1993, 45(3): 189-194.
[17] Steigleder Karl Z, Engel Dusan J. Hydrocracking process for liquefaction of lignin[P]. US4647704(1987).
[18] Funazukuri T, Wakao N, Smith J M. Liquefaction of lignin sulfonate with subcritical and supercritical water[J]. Fuel, 1990, 69(3): 349-353.
[19] Miller J E, Evans L, Littlewolf A, et al. Batch microreactor studies of lignin and lignin model compound depolymerization by bases in alcohol solvents[J]. Fuel, 1999, 78: 1363-1366.
[20] Saisu M, Sato T, Watanabe M, et al. Conversion of lignin with supercritical water-phenol mixtures[J]. Energy & Fuel, 2003, 17: 922-928.
[21] Akash B A, Muchore C B, Koropchak J A, et al. Investigation of simultaneous coal and lignin liquefaction–Kinetic studies[J]. Energy & Fuel, 1992, 6(5): 629-634.
[22] Cetin N S, Ozmen N. Use of organsolv lignin in phenol-formaldehyde resins for particleboard production[J]. International Journal of adhesion and adhesives, 2002, (22): 477-480.
[23] Alma M H. The use of wheat straw-phenol condensation products as molded materials[J]. Journal of Polymer Engineering, 1997, 17(4): 311-322.
[24] Maldas D,Shiraishi N.Liquefaction of biomass in the presence of phenol and H2O using alkalies and salts as the catalyst[J]. Biomass and Bioenergy. 1997, 12(4): 273-279.
[25] 朱臻, 程贤甦. 木质素改性高耐磨酚醛树脂的制备及性能研究[J]. 纤维素科学与技术, 2011, 19(1): 13-18.
[26] Matuana L M, Riedl B, Barry A O. Caracterisation cinetique par analyse enthalpique differentielle des resines phenol-formaldehyde a base de lignosulfonates[J]. Europ Polym Journal, 1993, 29(4): 483-490.
[27] 王明存. 木质素超临界溶剂降解反应及其在酚醛树脂合成中的应用[J]. 高分子学报, 2011, (12): 1433-1438.
[28] Nada A M A, Fadly M, Dawy M. Spertroscopic study of the molecular structure of a lignin-polymer system[J]. Polym Deg and Stab, 1992, 3(2): 125-129.
[29] 刘德启. 草浆造纸黑液改性制备木质素酚醛树脂结合剂[J]. 耐火材料, 2000, 34(6): 337-339.
[30] 黄进, 周紫燕. 木质素改性高分子材料研究进展[J]. 高分子通报, 2007, (1): 55-56.
[31] Alma M H,Yao Y G,Yoshioka M,et a1.The preparation and flow properties of HCL catalyzed phenolated wood and its blends with commercial novolak resin[J].Holzforschung, 1996, 50(1): 85-90.
[32] Peng W, Riedl B. The chemorheology of phenol- formaldehyde thermoset resin and mixtures of the resin with lignin fillers[J]. Polymer, 1994, 5(6): 1280-1286.
[33] 陈艳艳, 常杰, 范娟. 秸秆酶解木质素制备木材胶黏剂工艺[J]. 化工进展, 2011, 30(S1): 306-312.
[34] Zheng Z B, Cheng X S, Fu J, et al. Research on Phenol–Formaldehyde Adhesive Modified by Enzymatic Hydrolysis Lignin[C]. International Conference on Biomass Energy Technologies, Guang Zhou, 2008: 448-452.
[35] Jin Y Q, Cheng X S, Zheng Z B. Preparation and characterization of phenol–formaldehyde adhesives modified with enzymatic hydrolysis lignin[J]. Bioresource Technology, 2010, 101(6): 2046-2048.
[36] 胡立红, 周永红, 刘红军. 热塑性木质素酚醛树脂固化动力学研究[J]. 中国塑料, 2008, 22(08): 22-25.
[37] 王迪珍, 卜忠东, 杨兆禧. 木质素树脂/线型酚醛树脂模压材料的研究[J]. 高分子材料科学与工程, 1996, (3): 104-109.
[38] 胡立红, 周永红, 冯国东, 等. 木质素酚醛模塑料的性能研究[J]. 生物质化学工程, 2009, 43(4): 25-28.
[39] Lee W J. Properties of compression-molded plates made from wood powders impregnated with liquefied wood- based novolak-type phenol–formaldehyde resins[J]. Journal of Applied Polymer Science, 2010, 118(6): 3471-3476.
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