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Catalytic Conversion of Glucose to 5-Hydroxymethyl Furfural by 1,3-Disulfonic Acid Imidazolium Tetrachloroaluminate
Received date: 2014-04-20
Revised date: 2014-06-24
Online published: 2014-06-30
1,3-Disulfonic acid imidazolium tetrachloroaluminate {[Dsim]AlCl4} is a novel analogue of sulfonic acid functionalized imidazolium salts (SAFIS) with Bronsted acidic and Lewis acidic properties. In this work, 1,3-Disulfonic acid imidazolium tetrachloroaluminate is synthesized, and catalyzes the conversion of glucose into 5-hydroxymethyl furfural (5-HMF). The reaction temperature, reaction time and catalyst amount play key roles in the conversion of glucose into 5-HMF. Increasing the reaction temperature can shorten the reaction time. Further extending the reaction time, the yield of 5-HMF will decrease. A 5-HMF yield of 52.1% can be achieved under an optimum condition (140oC, 30 min). In addition, kinetic analysis reveals that the reaction is second ordered and the activation energy is 138 kJ•mol-1.This study is instructive for the conversion of glucose into 5-HMF using imidazolium salts.
CHEN Jia-yi , ZHONG Jia-wei , LI Ke-gui , HUANG Xing . Catalytic Conversion of Glucose to 5-Hydroxymethyl Furfural by 1,3-Disulfonic Acid Imidazolium Tetrachloroaluminate[J]. Advances in New and Renewable Energy, 2014 , 2(3) : 239 -244 . DOI: 10.3969/j.issn.2095-560X.2014.03.013
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