Advances in New and Renewable Energy >
Sulfate-Methanesulfonic Acid Mixed Electrolytes for the Negative Electrolyte of Vanadium Battery
Received date: 2014-04-25
Revised date: 2014-05-06
Online published: 2014-08-30
The effects of the sulfate-methanesulfonic acid mixed electrolytes on the electrochemical performance, stability, kinetic viscosity and cell performance of the negative electrolytes are studied. The results indicate the sulfate-methanesulfonic acid mixed electrolytes could improve the reversibility of the V(II)/V(III) redox couple, delay the time for crystal at low temperature, and decrease the kinetic viscosity of the electrolytes. However, it would decrease the coulombic efficiency of battery, promote the migration of the vanadium ion, and accelerate the decay of capacity and energy.
Key words: Vanadium battery; methanesulfonic acid; negative electrolyte
CHEN Yong , LIU Su-qin , HAN Hui-guo , LIU Jian-lei . Sulfate-Methanesulfonic Acid Mixed Electrolytes for the Negative Electrolyte of Vanadium Battery[J]. Advances in New and Renewable Energy, 2014 , 2(4) : 322 -326 . DOI: 10.3969/j.issn.2095-560X.2014.04.013
[1] 刘素琴, 黄可龙, 刘又年, 等. 储能机液流电池研发热点及前景[J]. 电池, 2005, 35(5): 356-359.
[2] Yang Z, Zhang J, Kintner-Meyer M C W, et al. Electrochemical energy storage for green grid[J]. Chemical Reviews, 2011, 111(5): 3577-3613.
[3] Skyllas-Kazacos M, Chakrabarti M H, Hajimolana S A, et al. Progress in flow battery research and development[J]. Journal of the Electrochemical Society, 2011, 158(8): R55-R79.
[4] 褚德成, 姚立为. 全钒氧化还原贮能电池制备方法的研究[J]. 应用能源技术, 2000, (2): 13-14.
[5] 张华民, 周汉涛, 赵平, 等. 储能技术的研究开发现状及展望[J]. 能源工程, 2005, (3): 1-7.
[6] 赵平, 张华民, 王宏, 等. 全钒液流储能电池研究现状及展望[J]. 沈阳理工大学学报, 2009, 28(2): 1-6.
[7] Sum E, Skyllas-Kazaco M.. A study of the V(II)/(III) redox couple for redox flow cell application[J]. Journal of Power Source, 1985, 15(5): 179-190.
[8] Skyllas-Kazacos M, Kasherman D, Hong D R, et al. Characteristics and performance of 1 kW UNSW vanadium redox battery[J]. Journal of Power Sources, 1991, 35(4): 399-404.
[9] 管涛, 林茂财, 余晴春. 添加剂对电解液及钒电池性能的影响[J]. 电池, 2011, 41(6): 325-327.
[10] 刘联, 刘效疆, 李晓兵, 等. 对甲苯磺酸对钒电池负极液的影响[J]. 电源技术, 2010, 34(6): 552-555.
[11] 李小山, 谢晓峰, 吕亚非. 全钒液流电池阴极电解液稳定性[J]. 化工学报,2011, 62(S2): 140-143.
[12] Li L Y, Kim S, Wang W, et al. A stable vanadium redox-flow battery with high energy density for large-scale energy storage[J]. Advance Energy Materials, 2011, 1(3): 394-400.
[13] Peng S, Wang N F, Wu X J, et al. Vanadium species in CH3SO3H and H2SO4 mixed acid as the supporting electrolyte for vanadium redox flow battery[J]. International Journal of Electrochemical Science, 2012, 7(1): 643-649.
/
〈 |
|
〉 |