A Review on Development of Dry Desulfurization Materials for DeSOx Filter in Diesel Exhaust

LIU Xue-cheng; HUANG Hong-yu; OSAKA Yugo; HE Zhao-hong; YANG Xi-xian; WANG Zhi-hui; WANG Nan-nan

doi:10.3969/j.issn.2095-560X.2015.04.009

Advances in New and Renewable Energy >

2015 , Vol. 3 >Issue 4: 299 - 304

DOI: https://doi.org/10.3969/j.issn.2095-560X.2015.04.009

A Review on Development of Dry Desulfurization Materials for DeSOx Filter in Diesel Exhaust

LIU Xue-cheng ,
HUANG Hong-yu ,
OSAKA Yugo ,
HE Zhao-hong ,
YANG Xi-xian ,
WANG Zhi-hui ,
WANG Nan-nan

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1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
2. Kanazawa University, Kakuma, Kanazawa, Ishikawa 9201192, Japan

Received date: 2015-06-16

Revised date: 2015-07-27

Online published: 2015-08-30

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Abstract

NOx removal catalysts in the diesel engine exhaust system are sulfur-sensitive. The DeSOx filter upstream of NOx removal system can capture SOx to prevent NOx removal catalysts from SOx poisoning in diesel engine exhaust. This paper is oriented toward some main dry desulfurization materials for DeSOx filter in diesel exhaust system, such as precious metal catalyst, metal carbonate and metal oxide. We laid emphasis on the desulfurization mechanism and performance of each material. The research status and industrial application prospect of those materials were also analyzed. It is pointed out that the cheap metal oxides with good desulfurization performance are appropriate for applications in the diesel DeSOx filters.

Key words： diesel exhaust system; DeSOx filter; dry desulfurization materials; desulfurization mechanism

Cite this article

LIU Xue-cheng , HUANG Hong-yu , OSAKA Yugo , HE Zhao-hong , YANG Xi-xian , WANG Zhi-hui , WANG Nan-nan . A Review on Development of Dry Desulfurization Materials for DeSOx Filter in Diesel Exhaust[J]. Advances in New and Renewable Energy, 2015 , 3(4) : 299 -304 . DOI: 10.3969/j.issn.2095-560X.2015.04.009

References

[1] Fang H, Wang J, Yu R, et al. Sulfur management of NOx adsorber technology for diesel light-duty vehicle and truck applications[J]. SAE Technical Papers, 2003, 01: 3245.

[2] Kim D H. Sulfation and desulfation mechanisms on Pt-BaO/Al2O3 NOx storage-reduction (NSR) catalysts[J]. Catalysis Surveys from Asia, 2014, 18(1): 13-23.

[3] Ottinger N A, Toops T J, Pihl J A, et al. Sulfate storage and stability on representative commercial lean NOx trap components[J]. Applied Catalysis B:Environmental, 2012, 117: 167-176.

[4] Wang Q, Zhu J H, Wei S Y, et al. Sulfur poisoning and regeneration of NOx storage-reduction Cu/K2Ti2O5 catalyst[J]. Industrial & Engineering Chemistry Research, 2010, 49(16): 7330-7335.

[5] Olsson L, Fredriksson M, Blint R J. Kinetic modeling of sulfur poisoning and regeneration of lean NOx traps[J]. Applied Catalysis B: Environmental, 2010, 100(1/2): 31-41.

[6] Choi J S, Partridge W P, Pihl J A, et al. Sulfur and temperature effects on the spatial distribution of reactions inside a lean NOx trap and resulting changes in global performance[J]. Catalysis Today, 2008, 136(1/2): 173-182.

[7] Limousy L, Mahzoul H, Brilhac J F, et al. SO2 sorption on fresh and aged SOx traps[J]. Applied Catalysis B: Environmental, 2003, 42(3): 237-249.

[8] Happel M, Kylhammar L, Carlsson P A, et al. SOx storage and release kinetics for ceria-supported platinum[J]. Applied Catalysis B: Environmental, 2009, 91(3/4): 679-682.

[9] Centi G, Perathoner S. Dynamics of SO2 adsorption–oxidation in SOx traps for the protection of NOx adsorbers in diesel engine emissions[J]. Catalysis Today, 2006, 112(1/4): 174-179.

[10] Limousy L, Mahzoul H, Brilhac J F, et al. A study of the regeneration of fresh and aged SOx adsorbers under reducing conditions[J]. Applied Catalysis B: Environmental, 2003, 45(3): 169-179.

[11] Nakatsuji T, Yasukawa R, Tabata K, et al. Highly durable NOx reduction system and catalysts for NOx storage reduction system[J]. SAE Technical Paper 980932, 1998, doi:10.4271/980932.

[12] Li L, King D L. Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control[J]. Applied Catalysis B: Environmental, 2010, 100(1/2): 238-244.

[13] Chansai S, Burch R, Hardacre C. Controlling the sulfur poisoning of Ag/Al2O3 catalysts for the hydrocarbon SCR reaction by using a regenerable SOx trap[J]. Topics in Catalysis, 2013, 56(1/8): 243-248.

[14] Nakatsuji T, Yasukawa R, Tabata K, et al. Catalytic reduction system of NOx in exhaust gases from diesel engines with secondary fuel injection[J]. Applied Catalysis B: Environmental, 1998, 17(4): 333-345.

[15] Meunier F C, Ross J R H. Effect of ex situ treatments with SO2 on the activity of a low loading silver-alumina catalyst for the selective reduction of NO and NO2 by propene[J]. Applied Catalysis B: Environmental, 2000, 24(1): 23-32.

[16] Nakatsuji T, Yasukawa R, Tabata K, et al. A highly durable catalytic NOx reduction in the presence of SOx using periodic two steps, an operation in oxidizing conditions and a relatively short operation in reducing conditions[J]. Applied Catalysis B: Environmental, 1999, 21(2): 121-131.

[17] Yoshida K, Asanuma T, Nishioka H, et al. Development of NOx reduction system for diesel aftertreatment with sulfur trap catalyst[J]. SAE Technical Paper, 2007, 01: 0237.

[18] Nishioka H, Asanuma T, Fukuma T. Development of clean diesel NOx after-treatment system with sulfur trap catalyst[J]. SAE International Journal of Fuels and Lubricants, 2010, 3(1): 30-36.

[19] Milne C R, Silcox G D, Pershing D W, et al. High-temperature, short-time sulfation of calcium-based sorbents. 1. Theoretical sulfation model[J]. Industrial & Engineering Chemistry Research, 1990, 29(11): 2192-2201.

[20] Borgward R h, Harvey R D. Properties of carbonate rocks related to SO2 reactivity[J]. Environmental Science & Technology, 1972, 6(4): 350-360.

[21] Li L, Chen Z M, Zhang Y H, et al. Kinetics and mechanism of heterogeneous oxidation of sulfur dioxide by ozone on surface of calcium carbonate[J]. Atmospheric Chemistry and Physics, 2006, 6: 2453-2464.

[22] Osaka Y, Kurahara S, Kobayashi N, et al. Study on SO2-absorption behavior of composite materials for DeSO(x) filter from diesel exhaust[J]. Heat Transfer Engineering, 2015, 36(3): 325-332.

[23] 冯亚娜, 赵毅. 金属氧化物在脱硫脱氮技术中的应用[J]. 工业安全与环保, 2003, 29: 3-6.

[24] Kylhammar L, Carlsson P A, Ingelsten H H, et al. Regenerable ceria-based SOx traps for sulfur removal in lean exhausts[J]. Applied Catalysis B: Environmental, 2008, 84(1/2): 268-276.

[25] Waqif M, Pieplu A, Saur O, et al. Use of CeO2-Al2O3 as a SO2 sorbent[J]. Solid State Ionics, 1997, 95(1/2): 163-167.

[26] Waqif M, Bazin P, Saur O, et al. Study of ceria sulfation[J]. Applied Catalysis B: Environmental, 1997, 11(2): 193-205.

[27] Saur O, Bensitel M, Saad A B M, et al. The structure and stability of sulfated alumina and titania[J]. Journal of Catalysis, 1986, 99(1): 104-110.

[28] Bensitel M, Saur O, Lavalley J C, et al. An infrared study of sulfated zirconia[J]. Materials Chemistry and Physics, 1988, 19(1/2): 147-156.

[29] Bensitel M, Waqif M, Saur O, et al. The structure of sulfate species on magnesium oxide[J]. The Journal of Physical Chemistry, 1989, 93(18): 6581-6582.

[30] Waqif M, Saur O, Lavalley J C, et al. Evaluation of magnesium aluminate spinel as a sulfur dioxide transfer catalyst[J]. Applied Catalysis, 1991, 71(2): 319-331.

[31] Li L Y, King D L. High-capacity sulfur dioxide absorbents for diesel emissions control[J]. Industrial & Engineering Chemistry Research, 2005, 44(1): 168-177.

[32] Li L, King D L. Cryptomelane as high-capacity sulfur dioxide absorbent for diesel emission control: A stability study[J]. Industrial & Engineering Chemistry Research, 2005, 44(19): 7388-7397.

[33] Li L, King D L. Synthesis and characterization of silver hollandite and its application in emission control[J]. Chemistry of Materials, 2005, 17(17): 4335-4343.

[34] Jiang R, Shan H, Li C, et al. Preparation and characterization of Mn/MgAlFe as transfer catalyst for SOx abatement[J]. Journal of Natural Gas Chemistry, 2011, 20(2): 191-197.

[35] Kang H T, Zhang C Y, Lv K, et al. Surfactant-assisted synthesis and catalytic activity for SOx abatement of high-surface-area CuMgAlCe mixed oxides[J]. Ceramics International, 2014, 40(4): 5357-5363.

[36] Yu H Q, Wu Y B, Song T B, et al. Preparation of metal oxide doped ACNFs and their adsorption performance for low concentration SO2[J]. International Journal of Minerals Metallurgy and Materials, 2013, 20(11): 1102-1106.

[37] Osaka Y, Tsujiguchi T, Kodama A, et al. Study on the optimized design of DeSOx filter operating at low temperature in diesel exhaust[J]. Journal of Chemical Engineering of Japan, 2014, 47(7): 555-560.

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