
0 引言
1 锑基硫属化合物材料及光电性质
1.1 材料性质
Fig. 1 The crystal structure diagram of Sb2Se3图1 硒化锑的晶体结构示意图 |
1.2 光电性质
2 锑基硫属化合物薄膜的制备
2.1 硒化锑
2.2 硫化锑
2.3 硒硫化锑
3 锑基硫属化合物薄膜缺陷特性及检测
3.1 缺陷特性
3.2 检测手段
Fig. 5 (a) Derivative -dC/dlnf versus frequency for various temperatures for the 5.91%-cell sample; (b) Arrhenius plots of ω0/T2 versus 1000/T for the three defects measured from the 5.91%-cell sample; (c) defect distribution of D1, D2, and D3 for the 5.91%-cell sample[37]图5 能量转换效率为5.91%的Sb2Se3太阳电池:(a)不同温度下的 -dC/dlnf与频率的比;(b)三种缺陷的阿伦尼乌斯曲线;(c)D1、D2和D3的缺陷分布[37] |
4 锑基硫属化合物太阳电池效率发展
4.1 硒化锑太阳电池
Fig. 6 The efficiency development of Sb2Se3 solar cells图6 Sb2Se3太阳电池能量转换效率的进展 |
4.2 硫化锑太阳电池
Fig. 7 The efficiency development of Sb2S3 solar cells图7 Sb2S3太阳电池能量转换效率的进展 |
4.3 硒硫化锑太阳电池
Fig. 8 The efficiency development of Sb2(S,Se)3 solar cells图8 Sb2(S,Se)3太阳电池效率进展 |
5 结论与展望
Table 2 Summary of antimony chalcogenide solar cells表2 锑基硫属化合物太阳电池汇总 |
锑基硫属 化合物 | 方法 | 器件结构 | 能量转换效率/ % | 开路电压 / mV | 短路电流 密度 / (mA/cm2) | 填充因子/ % | 文献 |
---|---|---|---|---|---|---|---|
Sb2Se3 | TE | FTO/CdS/Sb2Se3/Au | 1.90 | 300 | 13.20 | 48.0 | [74] |
FTO/CdS/Sb2Se3/Au | 3.70 | 335 | 24.40 | 46.8 | [75] | ||
ITO/ZnO/CdS/Sb2Se3/Au | 3.50 | 339 | 20.70 | 49.0 | [76] | ||
RTE | FTO/CdS/Sb2Se3/Au | 5.60 | 400 | 25.14 | 55.7 | [24] | |
ITO/CdS/Sb2Se3/PbS CQDs/Au | 6.50 | 427 | 25.5 | 59.3 | [89] | ||
FTO/TiO2/Sb2Se3/PbS CQDs/Au | 7.62 | 386 | 32.60 | 60.6 | [77] | ||
VTD | ITO/CdS/Sb2Se3/Au | 7.60 | 420 | 29.90 | 60.4 | [26] | |
ITO/CdS/Sb2Se3/CuSCN/Au | 7.50 | 423 | 30.10 | 57.0 | [78] | ||
Spin-coating | FTO/TiO2/CdS/Sb2Se3/Spiro-OMeTAD/Au | 3.90 | 340 | 27.20 | 41.9 | [79] | |
PLD | FTO/CdSe/Sb2Se3/Au | 3.65 | 357 | 20.18 | 50.7 | [80] | |
CSS | Mo/Sb2Se3/CdxZn1-xS/ZnO/AZO | 6.71 | 403 | 25.69 | 64.8 | [81] | |
Mo/MoSe2/Sb2Se3/TiO2/CdS/ZnO/AZO | 9.20 | 400 | 32.58 | 70.3 | [41] | ||
FTO/CdS:O/Sb2Se3/graphite/Ag | 7.01 | 432 | 29.87 | 54.0 | [82] | ||
FTO/TiO2/Sb2Se3/Au | 7.30 | 434 | 31.70 | 52.6 | [83] | ||
FTO/SnO2/CdS/Sb2Se3/t-Se/Au | 7.45 | 413 | 28.90 | 62.3 | [42] | ||
FTO/CdS/Sb2Se3/WO3-x/Au | 7.10 | 420 | 28.81 | 58.8 | [43] | ||
Sputtering | FTO/CdS/Sb2Se3/CuSbSe2/Au | 5.87 | 377 | 27.86 | 55.9 | [84] | |
Mo/Sb2Se3/CdS/ITO/Ag | 6.84 | 504 | 24.91 | 54.5 | [44] | ||
Sb2S3 | TE | FTO/CdS/Sb2S3/C-Ag | 1.27 | 600 | 6.10 | 35.0 | [47] |
FTO/TiO2/Sb2S3/Spiro-OMeTAD/Au | 1.69 | 599 | 6.43 | 44.0 | [48] | ||
VTD | ITO/CdS/Sb2S3/Au | 4.50 | 730 | 10.90 | 56.0 | [49] | |
ITO/CdS/Sb2S3/Au | 4.73 | 710 | 15.70 | 43.2 | [51] | ||
RTE | FTO/TiO2/Se-Sb2S3/Au | 5.40 | 690 | 11.53 | 51.2 | [50] | |
Mo/Sb2S3/CdS/i-ZO/AZO/Ni:Al | 1.75 | 658 | 7.09 | 37.6 | [52] | ||
Mo(MoSe2)/Sb2S3/CdS/iZO/AZO/Ni:Al | 1.86 | 466 | 13.60 | 31.1 | [53] | ||
Sputtering | Mo/Sb2S3/CdS/ITO/Ag | 0.95 | 308 | 10.33 | 30.8 | [54] | |
FCA | FTO/CdS/Sb2S3/Spiro-OMeTAD/Au | 4.30 | 632 | 12.93 | 52.4 | [57] | |
FTO/TiO2/Sb2S3/V2O5/Au | 4.80 | 590 | 15.29 | 52.9 | [58] | ||
Hydrothermal | FTO/CdS/Sb2S3/Spiro-OMeTAD/Au | 6.02 | 707 | 15.20 | 55.9 | [59] | |
Spin-coating | FTO/c-TiO2/Cs-Sb2S3/Spiro-OMeTAD/Au | 6.56 | 690 | 17.30 | 55.2 | [55] | |
FTO/c-TiO2/Zn-Sb2S3/Spiro-OMeTAD/Au | 6.35 | 647 | 17.19 | 57.1 | [56] | ||
FTO/TiO2/CdS/Sb2S3/Spiro-OMeTAD/Au | 6.40 | 760 | 15.11 | 56.1 | [60] | ||
FTO/TiO2/ZnCl2/Sb2S3/Spiro-OMeTAD/Au | 7.08 | 650 | 17.69 | 61.6 | [61] | ||
FTO/TiO2/Sb2S3/SbCl3/Spiro-OMeTAD/Au | 7.10 | 720 | 17.24 | 57.2 | [62] | ||
FTO/TiO2-bl/TiO2-mp/Sb2S3/PCPDTBT/Au | 6.40 | 596 | 16.10 | 66.5 | [92] | ||
Sb2(S,Se)3 | RTE | ITO/CdS/Sb2(Se1-xSx)3/Au | 5.79 | 500 | 22.30 | 52.2 | [65] |
FTO/ZnO/CdS/Sb2(Se1-xSx)3/Au | 5.73 | 480 | 21.89 | 54.5 | [66] | ||
VTD | ITO/CdS/Sb2(Se1-xSx)3/Au | 6.30 | 534 | 20.90 | 56.6 | [67] | |
ITO/CdS/Sb2(S,Se)3/Au | 7.27 | 460 | 29.60 | 54.2 | [68] | ||
Spin-coating | FTO/TiO2/BiI3:Sb2(S,Se)3/PEDOT:PSS/Au | 7.05 | 521 | 21.50 | 63.0 | [69] | |
FTO/c-TiO2/Sb2(S1-xSex)3/Spiro-OMeTAD/Au | 7.42 | 491 | 25.40 | 59.5 | [85] | ||
FTO/c-TiO2/In:CdS/Sb2(S1-xSex)3/Spiro-OMeTAD/Au | 6.63 | 590 | 18.14 | 62.4 | [86] | ||
CBD | FTO/c-TiO2/Sb2(S1-xSex)3/Spiro-OMeTAD/Au | 5.71 | 560 | 19.48 | 52.3 | [87] | |
Hydrothermal | FTO/TiO2/CdS/Sb2(Se1-xSx)3/Spiro-OMeTAD/Au | 5.73 | 792 | 12.03 | 60.9 | [70] | |
FTO/CdS/Sb2(S,Se)3/Spiro-OMeTAD/Au | 6.14 | 733 | 14.60 | 60.8 | [71] | ||
FTO/CdS/Sb2(S,Se)3/DTPThMe-ThTPA/Au | 9.69 | 638 | 23.19 | 65.5 | [88] | ||
FTO/CdS/Sb2(S,Se)3/Spiro-OMeTAD/Au | 10.10 | 630 | 23.70 | 67.7 | [59] | ||
FTO/CdS/Sb2(S,Se)3/Spiro-OMeTAD/Au | 10.50 | 664 | 23.80 | 66.3 | [72] |